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Strontium


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Atomic symbol: Sr
Atomic number: 38
Atomic weight: 87.62
Atomic volume: 33.7 cm3/mol
Density: 2.6 g/cm3
Period Number: 5
Group number: 2
Group name: Alkali Earth
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 1042.2 K
Boiling point: 1654 K
Heat of fusion: 8.30 kJ/mol
Heat of vaporization: 144.0 kJ/mol


Energies


Ionization Energy: 5.695 eV
1st ionization energy: 549.5 kJ/mole
2nd ionization energy: 1064.2 kJ/mole
3rd ionization energy: 4206.7 kJ/mole
Electronegativity: 0.95
Electron affinity: kJ/mole
Specific heat: 0.30 J/gK
Heat atomization: 164 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,8,2
Electron Shell Configuration: [Kr] 5s2
Minimum oxidation number: 0
Maximum oxidation number: 2
Minimum common oxidation number: 0
Maximum common oxidation no: 2


Appearance & Characteristics


Structure:: hcp: hexagonal close pkd
Color: silvery
Hardness: 1.8 mohs
Toxicity: ?
Characteristics: tarnishes
Uses: fireworks (red flame)


Reactions


Reaction with air: vigorous, =>SrO, Sr2N3
Reaction with 6M HCl: vigorous, =>H2, SrCl2
Reaction with 15M HNO3: vigorous, =>Sr(NO3)2, H2
Reaction with 6M NaOH: none


Other Forms


Number of isotopes: 4
Oxide(s): SrO
Hydride(s): SrH2
Chloride(s): SrCl2


Radius


Atomic Radius: 215 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): 132 pm
Ionic radius (3+ ion): pm


Conductivity


Thermal conductivity: 35.4 J/m-sec-deg
Electrical conductivity: 43.478 1/mohm-cm
Polarizability: 27.6 A^3


Abundance


Source: Celestite (sulfide)
Relative abundance solar system: 1.371 log
Abundance earth's crust: 2.6 log
Estimated crustal abundance: 3.70×102 milligrams per kilogram
Estimated oceanic abundance: 7.9 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(Named after Strontian, a town in Scotland.) Isolated by Davey by electrolysis in 1808, however, Adair Crawford recognized a new mineral (strontianite) as differing from other barium minerals in 1790 .


Properties


Strontium is softer than calcium and decomposes in water more vigorously. It does not absorb nitrogen below 3800C. It should be kept under kerosene to prevent oxidation. Freshly cut strontium has a silvery appearance, but rapidly turns a yellowish color with the formation of the oxide. The finely divided metal ignites spontaneously in air. Volatile strontium salts impart a beautiful crimson color to flames, and these salts are used in pyrotechnics and in the production of flares. Natural strontium is a mixture of four stable isotopes.


Uses


The major use for strontium at present is in producing glass for color television picture tubes. It has also found use in producing ferrite magnets and in refining zinc. Strontium titanate is an interesting optical material as it has an extremely high refractive index and an optical dispersion greater than that of diamond. It has been used as a gemstone, but is very soft. It does not occur naturally.


Forms


Strontium is found chiefly as celestite and strontianite. The metal can be prepared by electrolysis of the fused chloride mixed with potassium chloride, or is made by reducing strontium oxide with aluminum in a vacuum at a temperature at which strontium distills off. Three allotropic forms of the metal exist, with transition points at 235 and 5400C.


Isotopes


Sixteen other unstable isotopes are known to exist. Of greatest importance is 90Sr with a half-life of 29 years. It is a product of nuclear fallout and presents a health problem. This isotope is one of the best long-lived high-energy beta emitters known, and is used in SNAP (Systems for Nuclear Auxilliary Power) devices. These devices hold promise for use in space vehicles, remote weather stations, navigational buoys, etc., and where a lightweight, long-lived, nuclear-electric power source is needed.

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