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Neodymium


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Atomic symbol: 60
Atomic number: Nd
Atomic weight: 144.24
Atomic volume: 20.6 cm3/mol
Density: 7.0 g/cm3
Period Number: 6
Group number: none
Group name: Rare Earth, Lanthanides
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 1283.2 K
Boiling point: 3300 K
Heat of fusion: 7.140 kJ/mol
Heat of vaporization: 273.0 kJ/mol


Energies


Ionization Energy: 5.525 eV
1st ionization energy: 529.6 kJ/mole
2nd ionization energy: 1035 kJ/mole
3rd ionization energy: 2130 kJ/mole
Electronegativity: 1.14
Electron affinity: 50 kJ/mole
Specific heat: 0.19 J/gK
Heat atomization: 328 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,22,8,2
Electron Shell Configuration: [Xe] 4f4 6s2
Minimum oxidation number: 0
Maximum oxidation number: 3
Minimum common oxidation number: 0
Maximum common oxidation no: 3


Appearance & Characteristics


Structure:: cp: close packed (ABCB)
Color: silvery-white
Hardness: mohs
Toxicity: ?
Characteristics: ?
Uses: alloys, Welder's mask


Reactions


Reaction with air: vigorous, w/ht =>Nd2O3
Reaction with 6M HCl: mild, =>H2, NdCl3
Reaction with 15M HNO3: mild, =>Nd(NO3)3
Reaction with 6M NaOH: ?


Other Forms


Number of isotopes: 7
Oxide(s): Nd2O3
Hydride(s): NdH2 NdH3
Chloride(s): NdCl2 NdCl3


Radius


Atomic Radius: 181 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): 112.3 pm


Conductivity


Thermal conductivity: 16.5 J/m-sec-deg
Electrical conductivity: 15.4 1/mohm-cm
Polarizability: 31.4 A^3


Abundance


Source: Monazite(phosphate),bastnaesite
Relative abundance solar system: -0.082 log
Abundance earth's crust: 1.4 log
Estimated crustal abundance: 4.15×101 milligrams per kilogram
Estimated oceanic abundance: 2.8×10-6 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(Gr. neos: new, and didymos: twin) In 1841, Mosander, extracted a rose-colored oxide from cerite , which he believed contained a new element. He named the element didymium, as it was an inseparable twin brother of lanthanum. In 1885 von Welsbach separated didymium into two new elemental components, neodymia and praseodymia, by repeated fractionation of ammonium didymium nitrate. While the free metal is in misch metal, long known and used as a pyrophoric alloy for light flints, the element was not isolated in relatively pure form until 1925. Neodymium is present in misch metal to the extent of about 18%. It is present in the minerals monazite and bastnasite, which are principal sources of rare-earth metals.


Properties


The metal has a bright silvery metallic luster, Neodymium is one of the more reactive rare-earth metals and quickly tarnishes in air, forming an oxide that spalls off and exposes metal to oxidation. The metal, therefore, should be kept under light mineral oil or sealed in a plastic material. Neodymium exists in two allotropic forms, with a transformation from a double hexagonal to a body-centered cubic structure taking place at 8630C.


Uses


Didymium, of which neodymium is a component, is used for coloring glass to make welders goggles. By itself, neodymium colors glass delicate shades ranging from pure violet through wine-red and warm gray. Light transmitted through such glass shows unusually sharp absorption bands. The glass has been used in astronomical work to produce sharp bands by which spectral lines may be calibrated. Glass containing neodymium can be used as a laser material to produce coherent light. Neodymium salts are also used as a colorant for enamels.


Isotopes


Natural neodymium is a mixture of seven stable isotopes. Fourteen other radioactive isotopes are recognized.

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