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Gallium


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Atomic symbol: Ga
Atomic number: 31
Atomic weight: 69.723
Atomic volume: 11.8 cm3/mol
Density: 5.907 g/cm3
Period Number: 4
Group number: 13
Group name: Metal
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 302.98 K
Boiling point: 2676 K
Heat of fusion: 5.590 kJ/mol
Heat of vaporization: 258.70 kJ/mol


Energies


Ionization Energy: 5.999 eV
1st ionization energy: 578.8 kJ/mole
2nd ionization energy: 1978.9 kJ/mole
3rd ionization energy: 2963 kJ/mole
Electronegativity: 1.81
Electron affinity: 30 kJ/mole
Specific heat: 0.37 J/gK
Heat atomization: 286 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,3
Electron Shell Configuration: [Ar] 3d10 4s2 4p1
Minimum oxidation number: 0
Maximum oxidation number: 2
Minimum common oxidation number: 0
Maximum common oxidation no: 3


Appearance & Characteristics


Structure:: special: complex
Color: silvery-blue
Hardness: 1.5 mohs
Toxicity: ?
Characteristics: melts near r.t.wets glass
Uses: photocells, transistors


Reactions


Reaction with air: mild, =>Ga2O3
Reaction with 6M HCl: mild, =>GaCl3, H2
Reaction with 15M HNO3: ?
Reaction with 6M NaOH: mild, =>[Ga(OH)4]2-, H2


Other Forms


Number of isotopes: 2
Oxide(s): Ga2O3
Hydride(s): GaH3
Chloride(s): GaCl Ga2Cl6


Radius


Atomic Radius: 135 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): 76 pm


Conductivity


Thermal conductivity: 48.3 J/m-sec-deg
Electrical conductivity: 57.471 1/mohm-cm
Polarizability: 8.1 A^3


Abundance


Source: Bauxite (oxide)
Relative abundance solar system: 1.577 log
Abundance earth's crust: 1.2 log
Estimated crustal abundance: 1.9×101 milligrams per kilogram
Estimated oceanic abundance: 3×10-5 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(L. Gallia: France; also from Latin, gallus, a translation of "Lecoq", a cock) Predicted and described by Mendeleev as ekaaluminum, and discovered spectroscopically by Lecoq de Boisbaudran in 1875, who in the same year obtained the free metal by electrolysis of a solution of the hydroxide in KOH.


Sources


Gallium is often found as a trace element in diaspore, sphalerite, germanite, bauxite, and coal. Some flue dusts from burning coal have been shown to contain as much 1.5 percent gallium.


Properties


It is one of four metals -- mercury , cesium , and rubidium -- which can be liquid near room temperature and, thus, can be used in high-temperature thermometers. It has one of the longest liquid ranges of any metal and has a low vapor pressure even at high temperatures.

There is a strong tendency for gallium to supercool below its freezing point. Therefore, seeding may be necessary to initiate solidification.

Ultra-pure gallium has a beautiful, silvery appearance, and the solid metal exhibits a conchoidal fracture similar to glass. The metal expands 3.1 percent on solidifying; therefore, it should not be stored in glass or metal containers, because they may break as the metal solidifies.

High-purity gallium is attacked only slowly by mineral acids.

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