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Chlorine


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Atomic symbol: Cl
Atomic number: 17
Atomic weight: 35.453
Atomic volume: 22.7 cm3/mol
Density: 0.003214 g/cm3
Period Number: 3
Group number: 17
Group name: Halogen
Element classification: Non-metal


States


Phase at room temperature: Gas
Melting Point: 172.22 K
Boiling point: 239.2 K
Heat of fusion: 3.203 kJ/mol
Heat of vaporization: 10.20 kJ/mol


Energies


Ionization Energy: 12.968 eV
1st ionization energy: 1251.1 kJ/mole
2nd ionization energy: 2297.3 kJ/mole
3rd ionization energy: 3821.8 kJ/mole
Electronegativity: 3.16
Electron affinity: 349 kJ/mole
Specific heat: 0.48 J/gK
Heat atomization: 121 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,7
Electron Shell Configuration: [Ne] 3s2 3p5
Minimum oxidation number: -1
Maximum oxidation number: 7
Minimum common oxidation number: -1
Maximum common oxidation no: 7


Appearance & Characteristics


Structure:: layers of Cl2
Color: greenish-yellow
Hardness: mohs
Toxicity: yes
Characteristics: diatomic(Cl2), corrosive
Uses: bleach (NaOCl), PVC pipe


Reactions


Reaction with air: none
Reaction with 6M HCl: mild, =>HOCl, Cl-
Reaction with 15M HNO3: mild, =>HClOx, NOxCl, NOx
Reaction with 6M NaOH: mild, =>OCl-, Cl-


Other Forms


Number of isotopes: 2
Oxide(s): Cl2O ClO2 Cl2O7
Hydride(s): HCl
Chloride(s): Cl2


Radius


Atomic Radius: 100 pm
Ionic radius (1- ion): 167 pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): pm


Conductivity


Thermal conductivity: 0.01 J/m-sec-deg
Electrical conductivity: 0 1/mohm-cm
Polarizability: 2.2 A^3


Abundance


Source: Halite, brine (misc)
Relative abundance solar system: 3.719 log
Abundance earth's crust: 2.1 log
Estimated crustal abundance: 1.45×102 milligrams per kilogram
Estimated oceanic abundance: 1.94×104 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(Gr. chloros: greenish yellow) Discovered in 1774 by Scheele, who thought it contained oxygen. Chlorine was named in 1810 by Davy, who insisted it was an element.


Sources


In nature it is found in the combined state only, chiefly with sodium as common salt (NaCl), carnallite, and sylvite.


Properties


It is a member of the halogen (salt-forming) group of elements and is obtained from chlorides by the action of oxidizing agents and more often by electrolysis; it is a greenish-yellow gas, combining directly with nearly all elements. At 100C one volume of water dissolves 3.10 volumes of chlorine, at 300C only 1.77 volumes.


Uses


Chlorine is widely used in making many everyday products. It is used for producing safe drinking water the world over. Even the smallest water supplies are now usually chlorinated.

It is also extensively used in the production of paper products, dyestuffs, textiles, petroleum products, medicines, antiseptics, insecticides, food, solvents, paints, plastics, and many other consumer products.

Most of the chlorine produced is used in the manufacture of chlorinated compounds for sanitation, pulp bleaching, disinfectants, and textile processing. Further use is in the manufacture of chlorates, chloroform, carbon tetrachloride, and in the extraction of bromine.

Organic chemistry demands much from chlorine, both as an oxidizing agent and in substitution, since it often brings many desired properties in an organic compound when substituted for hydrogen, as in one form of synthetic rubber.

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