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Actinium


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Atomic symbol: Ac
Atomic number: 89
Atomic weight: 227
Atomic volume: 22.54 cm3/mol
Density: 10.07 g/cm3
Period Number: 7
Group number: none
Group name: Actinide
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 1324 K (1051°C or 1924°F)
Boiling point: 3471 K (3198°C or 5788°F)
Heat of fusion: ?
Heat of vaporization: ?


Energies


Ionization Energy: 5.17 eV
1st ionization energy: 499 kJ/mole
2nd ionization energy: 1170 kJ/mole
3rd ionization energy: kJ/mole
Electronegativity: 1.1
Electron affinity: kJ/mole
Specific heat: ?
Heat atomization: 385 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,32,18,9,2
Electron Shell Configuration: [Rn]7s26d1
Minimum oxidation number: 0
Maximum oxidation number: 3
Minimum common oxidation number: 0
Maximum common oxidation no: 3


Appearance & Characteristics


Structure:: fcc: face-centered cubic
Color: silvery-white
Hardness: mohs
Toxicity: ?
Characteristics: Radioactive
Uses: thermoelectric power


Reactions


Reaction with air: mild, w/ht, =>Ac2O3
Reaction with 6M HCl: mild, =>H2, AcCl3
Reaction with 15M HNO3: mild, =>Ac(NO3)3
Reaction with 6M NaOH: ?


Other Forms


Number of isotopes: 2
Oxide(s): Ac2O3
Hydride(s): AcH2
Chloride(s): AcCl3


Radius


Atomic Radius: 187.8 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): 126 pm


Conductivity


Thermal conductivity: J/m-sec-deg
Electrical conductivity: 1/mohm-cm
Polarizability: 32.1 A^3


Abundance


Source: Synthetic(U-235 decay)
Relative abundance solar system: log
Abundance earth's crust: -9.3 log
Estimated crustal abundance: 5.5×10-10 mg/kg
Estimated oceanic abundance: No Data Available
 
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History


(Gr. aktis, aktinos, beam or ray). Discovered by Andre Debierne in 1899 and independently by F. Giesel in 1902. Occurs naturally in association with uranium minerals.


Sources


Actinium-227, a decay product of uranium-235, is a beta emitter with a 21.6-year half-life. Its principal decay products are thorium-227 (18.5-day half-life), radium-223 (11.4-day half-life), and a number of short-lived products including radon, bismuth, polonium, and lead isotopes. In equilibrium with its decay products, it is a powerful source of alpha rays. Actinium metal has been prepared by the reduction of actinium fluoride with lithium vapor at about 1100 to 1300-degrees C.

The chemical behavior of actinium is similar to that of the rare earths, particularly lanthanum. Purified actinium comes into equilibrium with its decay products at the end of 185 days, and then decays according to its 21.6-year half-life. It is about 150 times as active as radium, making it of value in the production of neutrons.


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